You’re in NY? Sorry, I’m several timezones to your east across that big puddle, making a phone call impractical.
Just noticed one other thing that might affect your situation. Looking at the path for that .jpg you searched for:
E:\CONTENT FOLDERS FOR DAZ\chain-mail-tunic\Content\Runtime\libraries\Pose\Camelot-Char
If you open up your /content folders for DAZ/ folder, I suspect you might find a separate folder for every product you’ve installed, which isn’t going to work.
The quick way to fix this would be to open two Explorer windows (looking at your actual files, not inside D|S) one window showing one of the paths (as mentioned upthread, just pick one) from the Content Directory Manager, the other showing the path above as far as /Content/. All you need to do is drag the contents of the /Content/ folder into the CDM location. There will probably be a “do you want to merge folders” query, go ahead and OK this. Repeat for every product named folder you have in the /content folders for DAZ/ folder. That should get everything into one of your mapped content locations.