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I copied a row of polygons from one object, and I need to assign it a new material without re doing the UVS... how is that done?
You can create a Shading Domain from any group of polygons, and assign a material to it, is that what you mean?
Select your polys, go to the Shading Domain tab, and create new. Give it a name, and assign a material, the SD will appear in the surfaces tab inside DS.